The Impact of Aqueous Medium on Gas Yields and Kinetic Behaviors of Hydrogen Isotope Fractionation during Organic Matter Thermal Degradation     

LU Shuangfang  WANG Min  XUE Haitao  LI Jijun  CHEN Fangwen  XU Qingxia 《《地质学报》英文版》2011,85(6):1466-1477

In order to recognize the impact of aqueous medium on gas yields and the kinetic behaviors of hydrogen isotope fractionation during organic matter thermal degradation, the gold tube apparatus was used to conduct thermal simulation experiments by mixing the nC18 with the water of different properties and proportions. The yields of natural gas components, the relation among hydrogen isotope composition of each component and the experimental temperatures vs. heating rates have been obtained, and the results indicate that under the higher temperature conditions, the hydrous experiment has obvious impact on gas yields, such as when more water is added, higher amounts of hydrocarbon gas and H2 are yielded, and the existence of water obviously prolongs the temperature interval with the existence of heavy hydrocarbon gas. It also shows that the hydrogen isotope of hydrocarbon gas generated by the hydrous experiment is obviously lighter than that generated by the anhydrous experiment, and with the increasing amount of added water, the δD value of hydrocarbon gas gradually decreases. Compared with gas yields, the variation of δD value is more sensitive to aqueous medium in the thermal simulation experiment. However, compared with the amount of the added water, the aqueous medium property has smaller impact on the gas yields, which still shows the inherit effect on hydrogen isotope composition of aqueous medium. Through the model simulation and the isotope fractionation behavior analysis, it is validated that the hydrogen isotope fractionation process can be well described by the chemical kinetic model. The difference of reaction fraction of normal methane and D-containing methane is large, corresponding to the same activation energy. The content of normal methane is obviously higher in the part with lower activation energy, while the content of D-containing methane is higher in the part with higher activation energy. Therefore, it will result in larger hydrogen isotope fractionation amplitude, and the δD values will be more sensitive to the variation of maturity. Meanwhile, the average activation energy of methane generation from nC18 in the hydrous experiment is higher than that in the anhydrous experiment, and the greater amount of added water, the larger the average activation energy of methane generation reaction. This has laid foundation for its exploratory application in the study of gas reservoir forming history and the gas-source correlation, which indicates the research and application prospects in this orientation.  相似文献   

基于RAGA的PPC模型在化探异常分析中的应用——以凤太矿集区为例          下载免费PDF全文

廖时理  张均  张利亚  姚涛 《地质找矿论丛》2011,26(1):90-95

化探数据处理的核心内容是地球化学背景与地球化学异常的合理区分,找矿信息提取将直接影响到成矿预测的结果.文章采用基于RAGA的PPC模型对凤太矿集区1:5万水系沉积物化探数据进行处理,初步探讨了投影寻踪聚类方法在地球化学异常识别与元素共生组合方面的应用,以及投影方向值所代表的地质意义.结果表明,PPC模型的化探异常识别效...  相似文献   

泉州城市表层土壤重金属的赋存形态及污染评价   总被引：3，自引：0，他引：3  

林燕萍  胡恭任  于瑞莲  张雪琴 《矿物岩石》2011,31(2)

本文采用改进的BCR连续提取法研究泉州市区表层土壤中17种重金属的形态分布特征,并运用地积累指数Igeo法、潜在生态危害指数法、次生相与原生相分布比值法(RSP)评价土壤中重金属元素的潜在生态危害。结果表明,Li,Ti,Fe,Sc,V,As,Sb,Sn主要以残渣态存在;Cr,Ni,Cu,Zn,Bi在可氧化态中占有大比例,但仍以残渣态为主;Pb以可还原态为主;Mn,Cd,Co在可还原态和残渣态中占有较大比例。根据地累积指数法和RSP,泉州土壤受到不同程度的Sc,Co,Ni,Cu,Cd,Sb,Pb污染;潜在生态危害指数表明泉州市城区受到轻微生态危害。  相似文献   

辽宁本溪晶花洞洞穴特征及形成时代     

秦亚  程新民  常建平  平智岚 《世界地质》2011,30(3):375-380

辽宁本溪晶花洞发育于中奥陶世马家沟组(O₂m)厚层灰岩中,主要受近SN、NE断裂控制,沿近SN断裂发育高度不同的4层洞穴。洞内沉积物以化学沉积为主,机械沉积较少。通过测定洞内外的温度、湿度及CO₂含量,对比研究发现洞穴封闭性较好,与外界大气循环较差。在与洞外干河河流阶地的高程及形成时代上的对比研究基础上,结合主洞所采年龄样的铀系法测年(111.5±5.3 ka),初步推断晶花洞主洞发育于晚更新世。  相似文献   

南水北调中线水源地河水地球化学特征与流域侵蚀   总被引：1，自引：0，他引：1  

徐志方  唐杨 《矿物岩石地球化学通报》2011,30(1):26-30

丹江口水库及其上游流域是南水北调中线工程的水源地,本文讨论了水源地河流水化学与锶同位素(87Sr/86Sr)组成变化特征,目的在于了解水源地流域河流地表水溶质的物质来源以及岩石风化侵蚀过程和人为活动的影响。流域内河流水化学组成以Ca2+、HCO3-为主,Mg2+和SO42-次之,反映了碳酸盐岩风化溶解起控制作用的典型特征。水化学分析表明水源地河水受到工农业活动等人为因素的影响;河流87Sr/86Sr同位素地球化学研究表明,流域岩石风化输入至少存在三个不同端员(硅酸岩、石灰岩和白云岩)之间的混合。水源地流域内硅酸岩和碳酸岩的风化侵蚀速率分别为38.6和4.4 t/km2.a,总岩石风化侵蚀速率高于全球河流平均值。  相似文献   

Environmental capacity of chemical oxygen demand in the Bohai Sea: modeling and calculation     

赵喜喜  王修林  石晓勇  李克强  丁东生 《中国海洋湖沼学报》2011,29(1):46-52

A three-dimensional advection-diffusion model coupled with the degradation process is established for describing the transport of chemical oxygen demand (COD). Comparison of the simulated distribution of COD at the surface in the Bohai Sea in August, 2001 with field observations, shows that the model simulates the dataset reasonably well. The Laizhou Bay, Bohai Bay, and Liaodong Bay were contaminated heavily near shore. Based on the optimal discharge flux method, the Environmental Capacity (EC) and allocate...  相似文献   

Chemical constituents of marine algal-derived endophytic fungus Exophiala oligosperma EN-21     

��P  ���  ������  ����� 《中国海洋湖沼学报》2011,29(1):63-67

Seven compounds (1–7) were identified from the cultivation of the endophytic fungus Exophiala oligosperma (EN-21) that was isolated from the inner tissue of the marine red alga Laurencia similis. Their structures were identified with spectroscopic and chemical methods as 2-phenoxynaphthalene (1), (2S, 3R, 4E, 8E)-1-O-β-D-glucopyranosyl-3-hydroxy-2-[(R)-2′-hydroxyoctadecanoyl] amino-9-methyl-4, 8-octadeca-diene (2), (22E,24R)-ergosta-7,22-dien-3β,5α,6β-triol (3), (22E, 24R)-3β, 5α, 9α-trihydroxy- ergosta-7, ...  相似文献   

近6 ka以来科尔沁沙地东部气候变化记录   总被引：4，自引：3，他引：1  

刘冰  靳鹤龄  孙忠 《中国沙漠》2011,31(6):1398-1405

 根据科尔沁沙地东部TL剖面磁化率、有机质、化学元素等气候代用指标的变化特征和14C测年结果,分析和讨论了科尔沁沙地6 ka BP以来的气候变化过程。实验数据显示,高频磁化率、低频磁化率、有机质、Al2O3含量变化趋势基本一致,且峰值段对应古土壤层,谷值段对应风成砂层。依据气候代用指标的变化将6 ka BP以来科尔沁沙地气候变化分为3个阶段：Ⅰ.6.0～4.2 ka BP,气候暖湿,夏季风逐渐增强,并占主导,冬季风较弱,与全新世大暖期对应,但存在百年尺度的气候波动,其中：6.0～5.6 ka BP,5.6～5.4 ka BP,4.9～4.2 ka BP气候暖湿;5.6～5.5 ka BP,5.4～4.9 ka BP气候相对冷干。Ⅱ.4.2～1.3 ka BP,气候相对暖湿,与上一阶段相比夏季风有所减弱,但仍强于冬季风,其间也存在次一级波动,3.7～3.6 ka BP,3.4～1.3 ka BP,气候相对暖湿,4.2～3.7 ka BP,3.6～3.4 ka BP气候相对干冷。Ⅲ.1.3～0.65 ka BP以来,气候波动频繁,后期有向暖湿发展的趋势。总体而言,区域气候变化与全球具有较好的一致性。  相似文献   

云南省2009/2010年秋冬季罕见干旱诊断分析   总被引：1，自引：0，他引：1  

黄慧君  李庆红  高月忠  钟爱华  陈红玉  李建美 《热带地理》2011,31(1)

利用气候诊断方法,对云南省2009/2010年秋冬季干旱的成因进行初步分析。结果表明:云南出现严重干旱与西太平洋副高、西风带环流等大气环流系统出现异常有直接关系。副高出现明显异常,较常年同期偏强、偏西,700hPa流场上孟加拉湾长时间为东北气流控制,不利于将暖湿气流输送到云南;2009/2010年秋冬北半球500hPa极涡偏于西半球,强度偏弱,不利于冷空气向云南输送,由于冷空气和暖湿气流的输送都受到阻碍,冷暖空气难以在云南上空交汇;云南上空为较干燥的气流控制、云南及孟加拉的OLR值偏高,对流活动受到抑制,降水云系偏少等是云南降雨异常偏少,高温干旱的重要原因。  相似文献   

基于形态学分析铅锌矿不同功能区土壤重金属元素的分布特征及污染评价   总被引：1，自引：1，他引：0  

郭世鸿  侯晓龙  邱海源  刘爱琴  马祥庆  王友生 《地质通报》2015,34(11):2047-2053

为掌握尤溪铅锌矿区土壤重金属元素分布特征和污染现状,通过采集尤溪铅锌矿不同功能区0~20cm表层土壤样品,测定土壤中Pb、Zn、Cd、Cu、Cr 5种重金属元素的总量及其化学形态,分析不同功能区土壤重金属污染及分布特征,同时采用次生相与原生相比值法(RSP)进行污染评价。结果表明,尤溪铅锌矿不同功能区土壤中Pb、Zn、Cd含量均超过国家土壤环境质量三级标准,废弃冶炼区土壤Cd、Cu、Pb、Zn含量均最高,分别为标准值的14.78、1.13、3.73、1.34倍,采矿区Cr含量最高,但未超过标准限值。重金属形态结果表明,相比其他元素,Cd弱酸提取态所占比例最高,Cu可交换态比例最高,Pb、Zn、Cr以残渣态为主。RSP法评价表明,不同重金属的污染程度表现为:Cu(1.15)Cd(0.80)Pb(0.59)Zn(0.57)Cr(0.54);不同功能区土壤重金属污染表现为:尾矿库区冶炼区废弃冶炼区采矿区。SPEF法评价表明,尤溪铅锌矿区受人为污染明显,采矿区和尾矿库区Zn污染最为严重,冶炼区和废弃冶炼区Pb污染最为严重,功能区污染顺序为:尾矿库区冶炼区废弃冶炼区采矿区。  相似文献